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Cobalt-Mediated Radical Polymerization of Acrylonitrile: Kinetics Investigations and DFT Calculations

✍ Scribed by Antoine Debuigne; Catherine Michaux; Christine Jérôme; Robert Jérôme; Rinaldo Poli; Christophe Detrembleur

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
545 KB
Volume
14
Category
Article
ISSN
0947-6539

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Isoprene-Assisted Radical Coupling of (C
Isoprene-Assisted Radical Coupling of (Co)polymers Prepared by Cobalt-Mediated Radical Polymerization
✍ Antoine Debuigne; Christine Jérôme; Christophe Detrembleur 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 286 KB 👁 2 views

## Abstract **Tackling blocks**: The isoprene‐assisted radical coupling (I‐ARC) of polymers prepared by cobalt‐mediated radical polymerization (see picture) is the first efficient radical coupling method that is not restricted to short chains. When applied to AB diblock copolymers, I‐ARC constitute