Cobalt complexes in aqueous solutions as dioxygen carriers
✍ Scribed by Maria Rosaria Tiné
- Book ID
- 113524072
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 572 KB
- Volume
- 256
- Category
- Article
- ISSN
- 0010-8545
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The electrochetiistry of cobalt hematoporphyrin with nitrogen-containing axial ligands has not been reported previously although some complexes with pyridine and cyanide have been investigated by spectrophotometry'. Unlike most complexes of cobalt(II1) which are not very labile, the hematoporphyrin
The mononuclear q l-dioxygen complex [CO(CN),O,]~-(A) decomposes in aqueous solution to the hydroxocomplex [Co(CN),OHI3-(B) and the hydroperoxo complex [Co(CN),O0Hl3-(C). The mechanism involves partial dissociation of A to give [CO(CN),]~-(E) which binds with unreacted A to give the q':ql-peroxo com