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Cobalt-Catalyzed Highly Regio- and Stereoselective Intermolecular Reductive Coupling of Alkynes with Conjugated Alkenes.

✍ Scribed by Chun-Chih Wang; Pao-Shun Lin; Chien-Hong Cheng

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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## Abstract Transition‐metal‐catalyzed coupling of two different Cο£ΏC Ο€ components through a metallacycle intermediate is a highly atom economical method to construct Cο£ΏC bonds in organic synthesis. The metal‐catalyzed coupling of an alkene and alkyne generally gives an Alder‐ene or reductive coupli