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Cobalt carbonyl and phase transfer catalyzed carbonylation of thiiranes

โœ Scribed by Calet, Serge.; Alper, Howard.; Petrignani, Jean Francois.; Arzoumanian, Henri.


Book ID
120543673
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
438 KB
Volume
6
Category
Article
ISSN
0276-7333

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Cobalt carbonyl catalyzed sRN1 carbonyla
โœ Jean-Jacques Brunet; Christian Sidot; Paul Caubere ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 213 KB

The phase transfer catalyzed, cobalt carbonyl catalyzed carbonylation (1 atm. P.) of aryl and vinyl bromides under photostimulation (350 nm) affords the corresponding unsaturated acids in high yield. Recent investigations have demonstrated that phase transfer catalysis is a useful technique in organ