Cobalt-arylphosphine hydroformylation catalysts: substituent effects on the stability of the carbon-phosphorus bond
β Scribed by Dubois, Robert A.; Garrou, Philip E.
- Book ID
- 126450876
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 823 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0276-7333
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The unimolecular rearrangement of XSnBP (X ΒΌ H, Li, BeH, BH 2 , CH 3 , NH 2 , OH, and F) to Sn@PX is considered using B3LYP and QCISD calculations. The theoretical findings suggest that the doubly bonded Sn@PX molecule is intrinsically more stable than the triply bonded XSnBP species, regardless of
The hydroformylation of 4 -and 5 -steroids, namely cholest-4-ene (1), 3β€-acetoxycholest-4-ene (2), 3β€-acetoxycholest-5-ene (3), and 3β€acetoxypregn-5-en-20-one (4), was studied using rhodium catalysts modified with P-donor ligands containing electron withdrawing substituents, such as tris(o-tert-buty