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Cobalamin-Mediated Reduction of cis - and trans -Dichloroethene, 1,1-Dichloroethene, and Vinyl Chloride in Homogeneous Aqueous Solution: Reaction Kinetics and Mechanistic Considerations

✍ Scribed by Glod, Guy; Brodmann, Urs; Angst, Werner; Holliger, Christof; Schwarzenbach, René P.


Book ID
126275034
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
222 KB
Volume
31
Category
Article
ISSN
0013-936X

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Kinetic studies on reactions of ozone with trans-1,2-dichloroethene (DCE) and vinyl chloride (VC) were performed in air. In the presence of scavengers of radicals, such as CHBCHO, the rates for both reactions are second order (first order in each reactant). Observed rate constants are (1.80 f 0.29)