Coammonolysis of silicon tetrachloride and trimethylchlorosilane
β Scribed by K. A. Andrianov; M. M. Il'in; V. N. Talanov; I. I. Zhurakovskaya
- Book ID
- 112451380
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 321 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Tellurium dioxide, trimethylchorosilane, acetyl chloride, or acetyl bromide in glacial acetic acid generated a homogeneous solution. Addition of cyclohexene produced trans-2-halocyclohexyl tellurium trihalides of excellent purity in 70% yield. With dichloromethane or ethanol-free chloroform the same
## Abstract Efficient and mild aldol additions of Ξ²βketo esters and malonates to aldehydes are described using two novel protocols in the presence of silicon tetrachloride and trimethylchlorosilane, respectively. Scope and limitations of the methods have been discussed. Moreover the stability of th