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Coagulation Kinetics and Structure Formation

✍ Scribed by Hans Sonntag, Klaus Strenge (auth.), B. Vincent (eds.)


Publisher
Springer US
Year
1987
Tongue
English
Leaves
189
Edition
1
Category
Library

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✦ Synopsis


Colloidal dispersions play a very important role in nature, industry, and daily life. Sometimes, long-term stability is observed or desired as in ferrotluids (composed of very small magnetic particles with radii of ~ 10 nm), which must be stable even in external fields. On the other hand, only short-term stable dispersions may be necessary during actual processing operations, for example, dispersions of magnetite particles during tape manufacture. The stability of dispersions and many of their physical properties are related to the interaction between the particles in the dispersion medium, which may contain surfactants or macromolecular species. If the net interparticle interaction forces are attractive, then aggregation may occur. Two general types of aggregation behavior may be distinguished: coagulation and flocculation. These two terms are frequently used synonymously but IUPAC has recommended the following definitions: Coagulation implies formation of compact aggregates, leading to the macroscopic separation. Flocculation implies the formation of a loose or open network, floc, which may or may not separate macroscopically. Flocculation brought about by the simultaneous coadsorption of polymer molecules on two (or more) particles is referred to as bridging flocculation. If coagulation results in the merging of two particles into one, as may occur with liquid droplets in emulsions, this process is referred to as coalescence.

✦ Table of Contents


Front Matter....Pages 1-11
Introduction....Pages 13-13
Interaction between Colloidal Particles....Pages 14-37
Diffusion of Colloidal Particles....Pages 38-57
Coagulation Kinetics....Pages 58-126
Structure Formation in Disperse Systems....Pages 127-182
Back Matter....Pages 183-191

✦ Subjects


Physical Chemistry;Chemistry/Food Science, general;Nuclear Physics, Heavy Ions, Hadrons;Classical Continuum Physics;Industrial Chemistry/Chemical Engineering


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