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CO2-“Neutral” Hydrogen Storage Based on Bicarbonates and Formates

✍ Scribed by Albert Boddien; Felix Gärtner; Christopher Federsel; Peter Sponholz; Dörthe Mellmann; Dr. Ralf Jackstell; Dr. Henrik Junge; Prof. Matthias Beller


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
350 KB
Volume
50
Category
Article
ISSN
0044-8249

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CO2 activation and reaction with hydroge
✍ J. Wambach; G. Illing; H.-J. Freund 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 541 KB

Upon adsorption of CO2 at Tr 90 K on Ni( 1 lo), the molecule weakly chemisorbs and undergoes a geometrical distortion, i.e. it bends into a nonlinear geometry. This geometrical distortion is triggered by electron transfer from the substrate to the molecule, accompanied by formation of an anionic CO;