✦ LIBER ✦

CO2 laser induced isomerization and photodissociation of 1,2-dichloroethylene

✍ Scribed by Keeichi Nagai; Mikio Katayama

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 448 KB
Volume: 51
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80414-4

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✦ Synopsis

Infrared photoisomerization of both trans-and cis-l.Z-dichioroethylene molecules sensitized by SF6 has been observed by using a CO2 laser. The direct infrared photoisomerization has also been observed for the trans molecule. The reaction rate of the sensitized photoisomerization increases by 6 times as compared with the direct process. The dielectric breakdown induced by an intense laser pulse enhances a dissociative reaction_

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