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Co-ordination polymers of bis(8-hydroxy-5-quinolylmethylene) sulphide (BHQS)

✍ Scribed by R.D. Patel; H.S. Patel; S.R. Patel


Book ID
103073589
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
245 KB
Volume
23
Category
Article
ISSN
0014-3057

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✦ Synopsis


Co-ordination polymers of bis(8-hydroxy-5-quinolylmethylene)sulphide have been prepared with Zn 2+, Cu 2+, N? +, Co 2+ and Mn 2+ ions and characterized by elemental analyses, by i.r. and diffuse reflectance spectral studies and by magnetic moment. The metal contents in all polymers are found to be consistent with 1 : 1 (metal:ligand) stoichiometry. The thermal behaviour of each of the co-ordination polymer has been studied by TGA in air up to 700~C.


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The volatile products formed when the coordination polymer of copper(I1) and bis-(8-hydroxy-5-quinoly1)methane was heated in vacuum at elevated preselected temperatures were examined. The amount of weight loss at each temperature was determined with a recording thermal balance a t each fixed tempera