Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant
โ Scribed by Zhang, Feng; Du, Peng; Chen, Jijun; Wang, Hongxiang; Luo, Qiang; Wan, Xiaobing
- Book ID
- 124052943
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 760 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1523-7060
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Palladium-catalyzed mtion of a silcncy~cloptvpane with an a@ tri@te under carbon monari& pr~ssum (10-20 atm) in HMPA and that with carbon monoxide in chloroform provides new synthetic routes to 1,4-dicarbonyl compounds and I-keto pimelates, respectively. The reaction of a sikqycycloprvpane with a vi
## Abstract 1,4โDiketones were prepared by ceriumโcatalyzed oxidative coupling of styrene with molecular oxygen and 1,3โdicarbonyl compounds. This twoโstep sequence was performed as a oneโpot procedure without isolation of the intermediate products. The first step is a metalโcatalyzed radical react