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Co-acquisition of hyperpolarised 13C and 15N NMR spectra

✍ Scribed by Iain J. Day; John C. Mitchell; Martin J. Snowden; Adrian L. Davis

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
220 KB
Volume
45
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Recent developments in dynamic nuclear polarisation now allow significant enhancements to be generated in the cryo solid state and transferred to the liquid state for detection at high resolution. We demonstrate that the Ardenkjaer–Larsen method can be extended by taking advantage of the properties of the trityl radicals used. It is possible to hyperpolarise ^13^C and ^15^N simultaneously in the solid state, and to maintain these hyperpolarisations through rapid dissolution into the liquid state. We demonstrate the almost simultaneous measurement of hyperpolarised ^13^C and hyperpolarised ^15^N NMR spectra. The prospects for further improvement of the method using contemporary technology are also discussed. Copyright © 2007 John Wiley & Sons, Ltd.

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