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CNDO/2 and INDO calculations of a reaction pathway for the sigmatropic [1, 5] H-shift in cyclopentadiene

✍ Scribed by J. R. Dobbelaere; J. W. Haan; H. M. Buck; G. J. Visser


Publisher
Springer
Year
1973
Tongue
English
Weight
219 KB
Volume
31
Category
Article
ISSN
1432-2234

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In the preparation of 5-[(2-hydroxyacyl)amino]-2,4,6-triiodo-l,3-benzenedicartmxamides la-h from 2a-h two conditions using stoichiometric amounts of base (method A -aq NaOH at 50 Β°C; method B -MeONa in DMF at r. t.) were used. Yields are good to excellent provided that the right conditions are chose