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C−N Bond Insertion of a Complexed Phosphinidene into a Bis(imine) − A Novel 2,3-Sigmatropic Shift

✍ Scribed by Mark J. M. Vlaar; Pieter Valkier; Marius Schakel; Andreas W. Ehlers; Martin Lutz; Anthony L. Spek; Koop Lammertsma


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
148 KB
Volume
2002
Category
Article
ISSN
1434-193X

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Insertion reaction of propene into RhH b
✍ Willian R. Rocha; Wagner B. De Almeida 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 387 KB 👁 2 views

Quantum mechanical calculations at the MP4 (SDQ) level using the BP86-optimized geometries were carried out to investigate the energies and reaction mechanism for the propene (CH 3 -C 1 H=CH 2 2 ) insertion reaction into the Rh-H bond, using the cis-HRh(CO)(PH 3 ) 2 compound as a model catalytic sp