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CLXX.—The nature of the alternating effect in carbon chains. Part VI. A study of the relative directive efficiencies of oxygen and fluorine in aromatic substitution

✍ Scribed by Holmes, Eric Leighton ;Ingold, Christopher Kelk


Book ID
125845542
Publisher
The Royal Society of Chemistry
Year
1926
Weight
441 KB
Volume
129
Category
Article
ISSN
0368-1769

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Experimental studies of the anomeric eff
✍ Harold Booth; J. Mark Dixon; Khedhair A. Khedhair 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 763 KB

A bstracr: The ring inversion equilibrium in carbomethoxycyclohexanne is compared with those in 2-carbomethoxytetrahydropyran and 2-carbomethoxypiperidine through a variable temperature nmr study of the positions of equilibria. The derived A%, values (kcal mol-t) of -1.24 (cyclohexane), -1.69 (tetra