Cluster size effects in models of the active site for stereospecific heterogeneous Ziegler-Natta polymerization

Analysis of models for the Ziegler-Natta

Analysis of models for the Ziegler-Natta stereospecific polymerization on the basis of non-bonded interactions at the catalytic site—I. The Cossee model

✍ P. Corradini; V. Barone; R. Fusco; G. Guerra 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 658 KB

Abstrmct--The model proposed by Cossee for Ziegler-Natta polymerization of propene is re-examined by computing the non-bonded energies for all sets of possible internal coordinates of the atoms at the catalytic site. For catalytic sites in the bulk of ( 110) surfaces of TiCI3-~, it is possible to ex