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Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters with Water Molecules †

✍ Scribed by Kim, Hugh I.; Goddard, William A.; Beauchamp, J. L.

Book ID
126018237
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
329 KB
Volume
110
Category
Article
ISSN
1089-5639

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Enthalpies and free energies of gas-phase clustering of one to ten water molecules about one acid molecule are predicted from thermodynamic considerations. The enthalpy of formation of the monohydrate, H2SOI-H20, -53.5 kJ/mol, compare favorably with recent calculations from quantum mechanics, -67 kJ