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Cluster Core-Level Binding-Energy Shifts: The Role of Lattice Strain

✍ Scribed by Richter, B.; Kuhlenbeck, H.; Freund, H.-J.; Bagus, P.


Book ID
111688561
Publisher
The American Physical Society
Year
2004
Tongue
English
Weight
157 KB
Volume
93
Category
Article
ISSN
0031-9007

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Chemical shifts of the core-level bindin
✍ Paul S. Bagus; G. Pacchioni; C. Sousa; T. Minerva; F. Parmigiani πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 535 KB

Cluster model wavefunctions for the alkaline-earth oxides are analyzed to determine the origin of the trend of the chemical shifts of the binding energies, BEs, of the metal core levels. Two cancelling initial states mechanisms in the oxides are responsible for the trend. One is the increase of the