Asymmetric cyclopolymerization of N-tert
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Makiko Seno; Toshiya Ikezumi; Takafumi Sumie; Yasuhito Masuda; Tsuneyuki Sato
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Article
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2000
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John Wiley and Sons
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English
β 162 KB
π 2 views
The radical polymerization of N-tert-butyl-N-allylacrylamide (t-BAA) was carried out in a dimethyl sulfoxide/H 2 O mixture in the presence of β€-cyclodextrin (β€-CD). The polymerization proceeded with the complete cyclization of the t-BAA unit and yielded optically active poly(t-BAA). The IR spectrum