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Click Polymerization: Facile Synthesis of Functional Poly(aroyltriazole)s by Metal-Free, Regioselective 1,3-Dipolar Polycycloaddition

✍ Scribed by Qin, Anjun; Jim, Cathy K. W.; Lu, Weixin; Lam, Jacky W. Y.; Häussler, Matthias; Dong, Yongqiang; Sung, Herman H. Y.; Williams, Ian D.; Wong, George K. L.; Tang, Ben Zhong

Book ID
120396584
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
264 KB
Volume
40
Category
Article
ISSN
0024-9297

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Metal-Free Alkyne Polyhydrothiolation: S
Metal-Free Alkyne Polyhydrothiolation: Synthesis of Functional Poly(vinylenesulfide)s with High Stereoregularity by Regioselective Thioclick Polymerization
✍ Cathy K. W. Jim; Anjun Qin; Jacky W. Y. Lam; Faisal Mahtab; Yong Yu; Ben Zhong T 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 354 KB

## Abstract A new synthetic route to sulfur‐rich polymers has been developed. The alkyne polyhydrothiolations of 4,4′‐thiodibenzenethiol (**1**) and arylene dipropiolates (**2**–**5**) mediated by amines proceed at room temperature in a regioselective fashion, furnishing sole anti‐Markovnikov produ