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Cleavage reaction of pentaborane(9). Formation of a new hypho triborane adduct

✍ Scribed by Kameda, Mitsuaki; Kodama, Goji


Book ID
126794877
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
700 KB
Volume
19
Category
Article
ISSN
0020-1669

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Organic synthesis using haloboration rea
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A haloboration adduct, formed by the reaction of B-iodo-9-borabicyclo[3.3. llnonanes with ethoxyethyne reacts with aldehydes chemoselectively under very mild conditions. The subsequent hydrolytic work-up affords--a&unsaturated esters in good yields. The transformation of aldehydes to two carbon-ho