Cleavage reaction of cyclic ethers by alkyl chlorosulfinates
โ Scribed by Hara, Yoshinori; Matsuda, Minoru
- Book ID
- 126397489
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 716 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Epoxides and tetrahydrofurans are cleaved with concomitant acylation to chloroalkyl esters using a reagent system composed of an organomercurial, aluminum metal and an acid chloride. The cleavage is promoted under mild conditions by a range of readily-available cyclic ~alkoxychloremercurials and aci
The aminoalkylation of carbonyl compounds with ternary iminium salts is of general interest [1 -9]. Recently, we have disclosed that the aminoalkylation of ketones, enamines, imines (derivatives of aldehydes, cyclic or acyclic ketones) and aromatic compounds provides the corresponding Mannich bases