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Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3

✍ Scribed by Osvaldo M.Teme Centurión; Lydia R. Galagovsky; Eduardo G. Gros

Book ID
116066001
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
409 KB
Volume
60
Category
Article
ISSN
0039-128X

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✍ Antoni Siewnski; Barbara Henggeler; Hans Richard Wolf; Bruno Frei; Oskar Jeger 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 588 KB

In, n \*-Excitation of the y, 6-epoxy-enone (E)-3 leads exclusively to the conformers (%)-3A + B. On 'n, n\*-excitation of (E)-3, in addition to (%)-3A + B, products &9 arising from a carbene intermediate e are formed. However. products of an isomerization via C(y),O-bond cleavage of the oxirane wer