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Cleavage of tert-butyldimethylsilyl ethers by tetrafluoroborate salts

✍ Scribed by Brian W. Metcalf; Joseph P. Burkhart; Karin Jund

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
129 KB
Volume
21
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Cleavage of tert-butyldimethylsilyl ethe
Cleavage of tert-butyldimethylsilyl ethers by chloride ion
✍ Jaume FarrΓ s; Carme Serra; Jaume Vilarrasa πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 181 KB

A general method for the selective cleavage of tert-butyldimethylsilyl ethers in the presence of tert-butyldiphenylsilyl ones has been established using a combination of H20 and a concentrated solution of LiCI in DMF at 90 Β°C. Since no acids, bases, reducing or oxidizing agents are used, the method