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Cleavage of Some Organosilicon Compounds by Formic Acid

โœ Scribed by Gilman, Henry; Oita, Katashi

Book ID
127134844
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
283 KB
Volume
77
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Reductive cleavage of azo compounds cata
Reductive cleavage of azo compounds catalyzed by commercial zinc dust using ammonium formate or formic acid
โœ Shankare Gowda; K Abiraj; D.Channe Gowda ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 56 KB

Azo compounds, both symmetric and unsymmetric, are cleaved to amine(s) by using commercial zinc dust and ammonium formate or formic acid in methanol, tetrahydrofuran or dioxane at room temperature. The reductive cleavage occurs without hydrogenolysis or hydrogenation of reducible moieties, such as -