Cleavage of Phenylphosphonothioates by Hydroxide Ion and by Micellar Iodosobenzoate
โ Scribed by Berg, Frederic J.; Moss, Robert A.; Yang, Yu-Chu; Zhang, Hongmei
- Book ID
- 126841630
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 402 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0743-7463
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
o-Iodosobenzoate and o-iodoxybenzoate ion (IBA and IBX, respectively) are turnover catalysts of hydrolyses of phosphonofluoridates and non-toxic simulants. Reactions of IBA with phosphonothioates are stoichiometric because sulfides (e.g. 4-methoxybenzenethiol) reduce IBA to o-iodobenzoate ion. Oxida
1,3-Dihydro-1-oxido-3-methyl-1,2,3-benziodoxaphosphole 3-oxide (4) and 1-H-1-oxido-5-methyl-1,2,3benziodoxathiole 3,3-dioxide (5) were used to cleave \(p\)-nitrophenyl diphenyl phosphate (PNPDPP) (2) in aqueous micellar cetyltrimethylammonium chloride (CTACI) in phosphate buffer at \(\mathrm{pH} 8\)