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Cleavage of methyl and benzyl ethers with thiotrimethylsilanes

✍ Scribed by Stephen Hanessian; Yvan Guindon


Book ID
104225379
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
228 KB
Volume
21
Category
Article
ISSN
0040-4039

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Triphenylphosphine hydrobromide was found to cleave the benzyl ethers derived from 1Β°, 2Β°alkyl, and aryl alcohols to the corresponding alcohols and benzyltriphenylphosphonium bromide in good yields. Alkene and allyl phosphonium salts were produced from the benzyl ethers with 3Β°alkyl and allyl groups