✦ LIBER ✦
Cleavage of an Ether Bond via β-Elimination of Ethanol from [(H2O)5CrCH2CH2OC2H5]2+ in Aqueous Solutions; A Pulse Radiolysis Study
✍ Scribed by Dr. Haim Cohen; Prof. Dr. Dan Meyerstein
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 325 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
temperature range 100-298 K were readily fitted using an isotropic Heisenberg model, H'= 2 J S , .Sz ( S , =Sz = 2) and g = 2.24. The spin exchange coupling constant J of -14(2) cm -I," 'I which is in excellent agreement with the value derived for deoxyhemerythrin,[61 indicates weak antiferromagnetic behavior. 1 is thus a very good model for the bonding of the Fe" centers in deoxyhemerythrin and confirms the structure proposed by Solomon et a1.161 and Stenkamp et al.["l 600 800 1000 1200 400 L90 580 670 760 850 h(nm] -X[nm]
[I] a) R.