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Cleaner Continuous Photo-Oxidation Using Singlet Oxygen in Supercritical Carbon Dioxide

✍ Scribed by Richard A. Bourne; Xue Han; Martyn Poliakoff; Michael W. George

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
389 KB
Volume
48
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

High pressure under the spotlight: A new milliliter‐scale reactor is developed for using supercritical CO~2~ to perform continuous photo‐oxidation reactions. Changing from a traditional microliter‐scale batch reaction to 8 hours of reaction using the new reactor gives a 3000‐fold scale‐up of the oxidation of α‐terpinene (see picture).magnified image

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