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Clean Manufacture of 2,4,6-Trinitrotoluene (TNT) via Improved Regioselectivity in the Nitration of Toluene

✍ Scribed by Millar, Ross W.; Arber, Anthony W.; Endsor, Robert M.; Hamid, Javid; Colclough, M. Eamon


Book ID
121467142
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
931 KB
Volume
29
Category
Article
ISSN
0737-0652

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A hydride Meisenheimer complex of 2,4,6-trinitrotoluene (TNT) (TNTH-) was synthesized using tetramethylammonium octahydroborate. TNT and TNTH-(as the tetramethylammonium salt) were analyzed by direct exposure probe mass spectrometry using electron impact (EI), chemical ionization (CI) and negative-i