Clean Carbonylations in Supercritical Carbon Dioxide. Part 1: Palladium-Catalyzed Alkoxycarbonylation of Allyl Bromide
β Scribed by Ruiqi Song; Jianqing Zeng; Bing Zhong
- Book ID
- 110396147
- Publisher
- Springer US
- Year
- 2002
- Tongue
- English
- Weight
- 101 KB
- Volume
- 82
- Category
- Article
- ISSN
- 1011-372X
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## Abstract The Pdβcatalyzed addition of carbon monoxide and carbon tetrachloride to 1βoctene gave coadduct [alkyl 2β(2, 2, 2βtrichloroethyl)octanoate] as the major product in supercritical carbon dioxide by using pyridine as the base. It was found that the selectivity and the yield of coadduct wer
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