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Clay-supported reagents; III the intermediacy of nitrous esters in the oxidation of alcohols by clay-supported ferric nitrate.

✍ Scribed by André Cornélis; Pierre-Yves Herzé; Pierre Laszlo


Book ID
104219576
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
151 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


Stereospecific lntermedlate nitrite formation occurs in the title reaction. QUANTITATIVE conversion of alcohols into carbonyl compounds can be effected conveniently, under mild reaction conditions, using ferric nitrate impregnated on K 10 bentonlte clay.


📜 SIMILAR VOLUMES


Reactions on solid supports part V : The
✍ Anthony H. Jackson; K.R.Nagaraja Rao; Elizabeth Smeaton 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 239 KB

Evidence is presented to show that the clay-catalysed thallium nitrate oxidation of a-methylpyrroles to a-formylpyrroles involves formation of an intermediate nitrate ester which subsequently undergoes elimination of nitrite,