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Classification of valence changes of trivalent rare earth ions in alkaline earth borates using artificial neural networks

✍ Scribed by Yu-Hua Qi; Lu Xu


Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
74 KB
Volume
45
Category
Article
ISSN
0169-7439

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✦ Synopsis


3q

2q Ž . The investigations of classification on the valence changes from RE to RE RE ' Eu, Sm, Yb, Tm in host com-Ž . pounds of alkaline earth borate were performed using artificial neural networks ANNs . For comparison, the common methods of pattern recognition, such as SIMCA, KNN, Fisher discriminant analysis and stepwise discriminant analysis were adopted. A learning set consisting of 24 host compounds and a test set consisting of 12 host compounds were characterized by eight crystal structure parameters. These parameters were reduced from 8 to 4 by leaps and bounds algorithm. The recognition rates from 87.5 to 95.8% and prediction capabilities from 75.0 to 91.7% were obtained. The results provided by ANN method were better than that achieved by the other four methods.