Classification of the isomeric shifts and quadrupole splittings in organic tin compounds
✍ Scribed by V. Kotkhekar; V. S. Shpinel
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1969
- Tongue
- English
- Weight
- 354 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-4766
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## Abstract The electronic parameters in the Mössbauer spectroscopy, electric field gradient (EFG), and change in the charge density at the nucleus site Δψ^2^(0) are evaluated on the basis of the CNDO/II method for various compounds of antimony and tin and compared with experimental data. The corre
hing the part&I quadrupole splitting v&es (PQS) for ~hgands such as CI-' CN-and NHj derived from Messbauer spectra of Fe(H) low spin compounds. the sign of Vzz is obtained for &qQ)Co lu'isoek&ro\_nic compokds of Co(IH) low spin. The.predicted:sigus of V&, are: tmns\_ [Cb(NH&CIsl+,posi~, [Co(NHs)&Il?