𝔖 Bobbio Scriptorium
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Classification of rearrangement mechanisms and dynamic stereochemistry

✍ Scribed by J. Brocas


Publisher
Springer
Year
1981
Tongue
English
Weight
866 KB
Volume
24
Category
Article
ISSN
0022-4715

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MP2(fc)/6-31G\*\* calculations on the ground and transition state structures for intramolecular rearrangements of formylcyclopropene found that circumambulation of the ring by a formyl group occurs through a high-energy (DE = 42.6 kcal mol Γ€1 ) intermediate with a structure similar to bicyclo[1.1.0]