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Classical versus Bridged Allyl Ligands in Magnesium Complexes: The Role of Solvent

โœ Scribed by Chmely, Stephen C.; Carlson, Christin N.; Hanusa, Timothy P.; Rheingold, Arnold L.

Book ID
126968059
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
460 KB
Volume
131
Category
Article
ISSN
0002-7863

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Role of bridging diamine linkers on the
Role of bridging diamine linkers on the rate of ligand substitution in a series of dinuclear PtII complexes
โœ D. Jaganyi; V. M. Munisamy; D. Reddy ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 215 KB ๐Ÿ‘ 1 views

## Abstract A series of dinuclear platinum^II^ complexes of the type [{__trans__โ€Pt(H~2~O)(NH~3~)~2~}~2~โ€NH~2~(CH~2~)~n~H~2~N]^4+^ (where __n__ = 2, 3, 4, and 6) were synthesized to investigate the influence of the bridging diamine linker on the reactivity of the platinum centers. The p__K__~a~ val