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Classical and quantum mechanical studies of the CO vibrations in CO/Cu(100)

✍ Scribed by S.C. Park; W.K. Park; J.M. Bowman


Book ID
117219498
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
165 KB
Volume
427-428
Category
Article
ISSN
0039-6028

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πŸ“œ SIMILAR VOLUMES


The origin of the shift in the Cξ—ΈO vibra
✍ P.S. Bagus; W. MΓΌller πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 545 KB

Two major contributions to the shift of the C-O stretch vibrational frequency between free CO and chemisorbed CO/C\*:(lOO) are identified. The overlap and consequent repulsion between the CO and metal orbit& leads to an increase in the frequency. The metal charge donation and dative bonding to CO 2-