## Abstract Allenic silyl ketene acetals 3 formed by conjugate 1,6โaddition of organocuprates to 2โpropenโ1โyl and 2โbutenโ1โyl 2โenโ4โynoates 1 and regioselective enolate capture with silyl electrophiles readily undergo [3,3]โIrelandโClaisen rearrangements to the 2โsubstituted methyl 3,4โdienoates
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Claisen rearrangements of lactonic (silyl) enolates: a new route to functionalized cycloalkenes
โ Scribed by Danishefsky, Samuel; Funk, Raymond L.; Kerwin, James F.
- Book ID
- 126312453
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 388 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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