✦ LIBER ✦

[Cl2FeS2MoO(S2)]2−, a Novel Bimetallic Complex with Unusual Electronic Structure and a Substituted Tetrachalcogenometalate as “Ligand”

✍ Scribed by Prof. Dr. Achim Müller; Dr. Sabyasachi Sarkar; Dr. Hartmut Bögge; Rainer Jostes; Prof. Dr. Alfred Trautwein; Uschi Lauer

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 234 KB
Volume: 22
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198305611

No coin nor oath required. For personal study only.

✦ Synopsis

product being condensed and collected in an ice-cooled receiver. The product is inhibited with p-methoxyphenol (500 ppm) and stripped of methanol and cyclopentadiene on a rotary evaporator keeping the temperature below 40 "C. Crystallization of the crude product from toluene/ hexane with carbon decolorization provides 3, m. p. 130-131°C in 85-90% yield; 'H-NMR (CDCl,, 60 MHz): 6=5.36 (ABq, JAB=1.4 Hz,JBC=11 Hz, lH), 5.96 (ABq, JA9=1.4, Jgc=18 HZ, IH), 6.75 (ABq, J,c=ll, JBc=18 6 = 116.46 (CH=CH2), 122.62 (C-4,5), 125.83 (CH=CH,), 146.51 (C-2).

Hz, 1 H), 7.13 (s, 2H); I3C-NMR (CDCl,, 100 MHz):

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