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C(K, X) as an M-ideal inWC(K, X)

✍ Scribed by T. S. S. R. K. Rao


Book ID
112906381
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1990
Tongue
English
Weight
386 KB
Volume
102
Category
Article
ISSN
0253-4134

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Hypermetallation is ubiquitous: MX6 mole
✍ Paul von R. Schleyer; JΓΌrgen Kapp πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 274 KB

The octahedral MX 6 hypermetallated clusters (M = C, Si, Ge, Sn, Pb and X = Li, Na, K) all are stable minima. The bonding in the entire set is similar, with considerable M-X + ionic character and cage XX interactions. Density functional computations (Becke3LYP/TZP; Sn, Pb = pseudopotential calculati