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Citral oxide and some of its reactions

✍ Scribed by L. P. Glushko; V. N. Samsonova; M. S. Malinovskii; L. A. Yanovskaya


Book ID
112443039
Publisher
Springer
Year
1980
Tongue
English
Weight
356 KB
Volume
29
Category
Article
ISSN
1573-9171

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The ‘Aldol Condensation’ of Citral and R
✍ Alan F. Thomas; Renée Guntz-Dubini 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 462 KB

## Abstract The reaction of citral with anhydrous base leads initially to a cyclohexa‐1,3‐dienecarbaldehyde. Stronger base and longer reaction times result in deconjugation to a cyclohexa‐1,4‐diene‐carbaldehyde, together with oxidative loss of six carbon atoms to yield 2‐methyl‐4‐(4‐methylpent‐3‐en