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Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide

✍ Scribed by Robson da Silva Vidal; Fábio Gorzoni Doro; Kleber Queiroz Ferreira; Zênis Novais da Rocha; Eduardo Ernesto Castellano; Sofia Nikolaou; Elia Tfouni

Book ID
113661915
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
300 KB
Volume
15
Category
Article
ISSN
1387-7003

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Mechanistic Insights into the cis–trans
Mechanistic Insights into the cis–trans Isomerization of Ruthenium Complexes Relevant to Catalysis of Olefin Metathesis
✍ Dr. Albert Poater; Dr. Francesco Ragone; Dr. Andrea Correa; Dr. Anna Szadkowska; 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 647 KB

## Abstract The mechanism of the __trans__ to __cis__ isomerization in Ru complexes with a chelating alkylidene group has been investigated by using a combined theoretical and experimental approach. Static DFT calculations suggest that a concerted single‐step mechanism is slightly favored over a mu