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cis,trans-Cyclohepta-1,3-diene as a transient intermediate in the photocyclization of cis,cis-cyclohepta-1,3-diene

โœ Scribed by Inoue, Yoshihisa; Hagiwara, Shoji; Daino, Yoshihiko; Hakushi, Tadao

Book ID
125811485
Publisher
The Royal Society of Chemistry
Year
1985
Tongue
English
Weight
309 KB
Volume
19
Category
Article
ISSN
0022-4936

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Intramolecular photocyclization of cis,
Intramolecular photocyclization of cis, cis- and trans, trans-cyclodeca-1,6-diene to anti tricyclo[5.3.0.02,6]decane.
โœ Arnon Shani ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 131 KB

The transannular photocyclization of the cis,cis-cyclodecs-1,6+lienes to the tricyolo 5.3.0.02p6 --C 3 decane (1) may be explained due to the proximity in space of the two double bonds in the ~~hamnocks conformation I (2). Hence, in an intramolecular photocyclization of the isomeric trans,trans,cycl