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cis-trans Isomerism of Exocyclic α,β-Unsaturated Indanones and Tetralones

✍ Scribed by Kevill, Dennis N.; Weiler, Ernest D.; Cromwell, Norman H.

Book ID
126258542
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
381 KB
Volume
29
Category
Article
ISSN
0022-3263

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✍ Kiyoto Hori; Hiroyasu Sugihar; Yoshio N. Ito; Tsutomu Katsuki 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 219 KB

Aziridination of (x,l~-unsamrated amides was effected by treatment with lithiated 3,3-pentamethylenediaziridine in high diastereoselectivity, c/s-Azin'dine was the predominant diastereomer irrespective of the geometry of the substrates. A stepwise mechanism, 1,4-addition of a lithiated diaziridine t