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Cis-trans isomerism in the pyridyl analogs of azobenzene. Kinetic and molecular orbital analysis

โœ Scribed by Brown, Ellis V.; Granneman, G. Richard


Book ID
111651979
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
907 KB
Volume
97
Category
Article
ISSN
0002-7863

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## Abstract New polydimethylsiloxanes with __p__โ€substituted azobenzene sideโ€groups were synthesized. Thin films and solutions exhibit a photochemical __transโ€cis__ isomerization of the azobenzene groups, followed by their __cisโ€trans__ thermal relaxation in the dark. In films, relaxation rates wer