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Cis – Trans Amide Bond Rotamers in β-Peptoids and Peptoids: Evaluation of Stereoelectronic Effects in Backbone and Side Chains

✍ Scribed by Laursen, Jonas S.; Engel-Andreasen, Jens; Fristrup, Peter; Harris, Pernille; Olsen, Christian A.

Book ID: 120520522
Publisher: American Chemical Society
Year: 2013
Tongue: English
Weight: 504 KB
Volume: 135
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja312532x

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## Abstract The configuration and hydrogen‐bonding network of side‐chain amides in a 35 kDa protein were determined by measuring differential and trans‐hydrogen‐bond H/D isotope effects by using the isotopomer‐selective (IS)‐TROSY technique, which leads to a reliable recognition and correction of e