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Cis-(hydrido)hydrocarbylplatinum(IV) complexes as intermediates in the PtIIC bond breaking

✍ Scribed by Vincenzo De Felice; Augusto De Renzi; Achille Panunzi; Diego Tesauro


Book ID
103230376
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
152 KB
Volume
488
Category
Article
ISSN
0022-328X

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Hydrido(3-hydroxyalkynyl) Complexes as I
✍ Emilio Bustelo; Manuel Jiménez-Tenorio; M. Carmen Puerta; Pedro Valerga 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 371 KB 👁 1 views

The reaction of propargyl alcohol derivatives with the complex [Cp\*RuCl(dippe)] [dippe = 1,2-bis(diisopropylphosphane)ethane] and NaBPh 4 in MeOH yields hydrido(3-hydroxyalkynyl) compounds [Cp\*Ru(H){CϵCC(OH)RRЈ}-(dippe)][BPh 4 ] [R, RЈ = Ph, Ph (1a); H, Ph (1b); H, Me (1c)]. These represent interm