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cis-Ethyl­enebis(diphenyl­phosphine oxide)

✍ Scribed by Caddy, Judy ;Coyanis, E. Mabel ;Fernandes, Manuel A. ;Khanye, Setshaba D. ;Omondi, Bernard

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
326 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~26~H~22~O~2~P~2~, crystallizes across a twofold rotation axis. The structure is characterized by chains formed through C—H...O hydrogen bonds running along the b axis, which are further supported by C—H...π and π–π intermolecular interactions.

📜 SIMILAR VOLUMES

Butyl­diphenyl­phosphine oxide
Butyl­diphenyl­phosphine oxide
✍ Caddy, Judy ;Coyanis, E. Mabel ;Lemmerer, Andreas ;Khanye, Setshaba D. ;Omondi, 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 190 KB
Dichloro­bis[(diphenyl­phosphinoethyl-κP
Dichloro­bis[(diphenyl­phosphinoethyl-κP)­diphenyl­phosphine oxide]digold(I)(Au—Au) monohydrate
✍ Xie, Zai-Lai ;Chen, Zhong-Ning 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 170 KB

In the title compound, [Au 2 Cl 2 (dppeo) 2 ]ÁH 2 O, where dppeo is (diphenylphosphinoethyl)diphenylphosphine oxide (C 26 H 24 -OP 2 ), each Au I center is two-coordinated by Cl and P donors and exhibits an approximately linear arrangement. The dppeo ligand adopts a monodentate bonding mode.

Thiol Elimination from Tris[2-(phenylthi
Thiol Elimination from Tris[2-(phenylthio)ethyl]phosphine Oxide: A Convenient Route to Trivinylphosphine Oxide.
✍ Nina K. Gusarova; Nataliya A. Chernysheva; Svetlana N. Arbuzova; Maria V. Bogdan 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 12 KB

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