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cis-Diazenes. Viscosity effects, one-bond scission, and cis-trans isomerization

✍ Scribed by Neuman, Robert C.; Grow, Richard H.; Binegar, Glen A.; Gunderson, Howard J.

Book ID
120333719
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
867 KB
Volume
55
Category
Article
ISSN
0022-3263

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The 1 H NMR study of fulleroproline derivative Ac-Fpr-OtBu and its Pro analogue Ac-L-Pro-OtBu over a range of temperatures in toluene-d 8 solution has enabled the comparison of their equilibrium and activation parameters for the trans/cis interconversion around the amide partial double bond.